| Head of Post | Title | Career | Appointment Date | Presentation of credentials | Termination of mission |
| Délisle, Jean-Louis | AE&P | C | 1961/03/16 | 1961/06/27 | 1964/05/26 |
| Olivier, William George Marcel | AE&P | C | 1964/08/13 | 1964/06/27 | 1966/07/31 |
| Hicks, Arthur John | AE&P | C | 1966/06/21 | 1966/10/13 | 1968/11/29 |
| Munro, Donald Wallace | AE&P | C | 1968/11/05 | 1968/12/19 | 1971/11/07 |
| Langille, Gilbert Craig | AE&P | C | 1971/08/25 | ||
| Magee, William Edward | Chargé d'Affaires a.i. | C | 1975/03/14 | 1975/12/03 | |
| Reynolds, Ralph Edward | AE&P | C | 1975/10/21 | 1975/12/03 | 1978/06/30 |
| Logie, Robert R.M. | Chargé d'Affaires a.i. | C | 1978/08/15 | 1979/09/04 | |
| Sirrs, Robert Douglas | AE&P | C | 1979/04/04 | 1979/09/04 | 1982/07/29 |
| Filleul, Francis Miles | AE&P | C | 1982/09/22 | ||
| Gooch, Stanley Edward | AE&P | C | 1986/07/23 | 1986/09/24 | 1989/07/15 |
| Pardy, Henry G. | AE&P | C | 1989/09/28 | 1992/09/10 | |
| Durand, Paul D. | AE&P | C | 1992/08/27 | 1992/09/29 | |
| Goodleaf, Dan E. | AE&P | C | 1995/00/00 | 1998/08/31 | |
| Thibault, Denis | AE&P | C | 1998/08/04 | 1998/09/08 | |
| Léger, Louise | AE&P | C | 2001/08/20 | 2001/10/10 | |
| Laguë, Mario | AE&P | C | 2004/09/14 | 2004/10/11 | |
| Reeder, Neil | AE&P | C | 2007/10/29 | ||
| MacKay, Cameron | AE&P | C | 2010/08/10 | ||
| Drukier, Wendy | AE&P | NC | 2012/08/20 |