| Head of Post | Title | Career | Appointment Date | Presentation of credentials | Termination of mission |
| Blake, Roy William | A/HC | C | 1962/09/07 | 1962/03/04 | |
| McInnes, Graham Campbell | HC | C | 1962/12/06 | 1963/03/04 | 1965/06/01 |
| Jay, Raymond Harry | HC | C | 1965/04/29 | 1965/07/27 | 1968/08/17 |
| Moore, Victor Campbell | HC | C | 1968/10/03 | 1968/10/21 | 1972/08/18 |
| Harrington, John Maurice | HC | C | 1972/05/23 | 1972/09/19 | 1976/08/19 |
| Hooper, Cleeve Francis Wilfrid | HC | C | 1976/09/14 | 1976/09/13 | 1978/10/02 |
| Sheehan, Terrence Bernard | HC | C | 1978/12/21 | 1981/07/25 | |
| Reece, David Chalmer | HC | C | 1982/09/22 | 1982/08/26 | 1985/08/19 |
| Woolham, Robert Gordon | HC | C | 1985/07/27 | 1985/09/05 | |
| McCallion, Kathryn Elizabeth | HC | C | 1987/07/30 | 1987/10/05 | 1990/08/24 |
| McQueen, Jennifer R. | HC | C | 1990/00/00 | 1990/10/10 | 1993/10/03 |
| Hewlett-Jobes, Kathryn | HC | C | 1993/06/23 | ||
| Stewart, Gavin Hugh | HC | C | 1996/04/03 | 1999/09/22 | |
| Robinson, John | HC | C | 1999/06/10 | ||
| Valle, Claudio | HC | C | 2003/07/15 | ||
| Kingsley, Denis | HC | C | 2006/07/13 | ||
| Hallihan, Stephen | AE&P | C | 2009/06/09 |