| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Menzies, Arthur Redpath | AEP | C | 1958/07/00 | 1958/09/03 | 1961/07/16 |
| Bissonnette, Pierre-André | Chargé d'affaires a.i. | C | 1961/07/16 | 1962/01/00 | |
| McGaughey, Charles Eustace | AEP | C | 1961/11/22 | ||
| Butler, Bertram Charles | AEP | C | 1965/03/25 | 1965/11/06 | 1967/08/11 |
| Hadwen, John Gaylard | AEP | C | 1967/08/03 | 1967/11/22 | 1971/07/31 |
| Rettie, Edward Rose | AEP | C | 1971/08/04 | ||
| Stansfield, David | AEP | C | 1974/06/13 | ||
| Bauer, William Edward | AEP | C | 1976/02/02 | 1976/08/09 | 1979/06/04 |
| Bild, M. Fred | AEP | C | 1979/04/04 | ||
| Wright, Arthur Robert | AEP | C | 1979/07/26 | 1979/10/27 | 1982/07/16 |
| Westdal, Christopher William | AEP | C | 1982/09/22 | ||
| Vincent, Anthony | AEP | C | 1985/11/21 | 1985/10/21 | 1988/09/02 |
| Gauvreau, Émile | AEP | C | 1988/12/07 | 1989/05/29 | 1992/08/05 |
| Perron, Arthur C. | AEP | C | 1992/00/00 | 1994/07/12 | |
| von Nostitz, Manfred Gustav | AEP | C | 1994/00/00 | 1997/06/23 | |
| Giroux, Bernard | AEP | C | 1997/10/30 | ||
| McAlister, Andrew | AEP | C | 2001/08/20 | 2002/10/04 | |
| Comeau, Denis | AEP | C | 2004/08/09 | 2005/05/13 | 2007/07/10 |
| Hoffmann, Ron | AEP | C | 2011/03/21 |