| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Pick, Alfred John | AEP | C | 1961/04/20 | 1961/07/17 | 1962/04/03 |
| Tovell, Freeman Massey | AEP | C | 1962/09/27 | 1963/02/06 | 1965/10/19 |
| Houde, Joseph François Xavier | AEP | C | 1965/09/02 | 1966/04/25 | 1970/08/07 |
| Charpentier, Pierre Edgar Joseph | AEP | C | 1970/06/18 | 1970/11/24 | 1973/08/11 |
| Trottier, Pierre L. | AEP | C | 1973/09/04 | 1973/12/18 | 1976/07/06 |
| Dier, Ormond Wilson | AEP | C | 1976/07/27 | 1976/12/10 | 1979/08/24 |
| Grenon, Jean-Yves | AEP | C | 1979/03/21 | 1980/03/05 | 1982/08/20 |
| Bell, Michael Richard | AEP | C | 1982/04/01 | 1982/06/01 | |
| Bezanson, Keith Arthur | AEP | C | 1985/08/07 | 1985/11/06 | 1988/04/00 |
| Charles, Margaret Anne | AEP | C | 1988/08/11 | 1988/10/13 | |
| Leach, James Darrell | AEP | C | 1990/00/00 | 1990/10/31 | |
| Vincent, Anthony | AEP | C | 1993/00/00 | 1994/03/09 | 1997/06/18 |
| McCue, Douglas | Chargé d'affaires a.i. | C | 1993/07/00 | 1994/03/00 | |
| Clark, Graeme C. | AEP | C | 1997/07/10 | 1997/09/02 | 2001/08/27 |
| Rousseau, Hugues | AEP | C | 2001/07/16 | 2001/09/07 | 2004/08/15 |
| des Rivières, Geniève | AEP | C | 2004/08/09 | 2004/09/30 | |
| Lecoq, Richard | AEP | C | 2008/10/28 |