| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Charpentier, Fulgence | AEP | C | 1962/03/01 | 1962/06/27 | 1965/07/05 |
| Blouin, Georges-Henri | AEP | C | 1965/05/04 | 1965/05/04 | 1967/07/02 |
| Thibault, J.E. | AEP | C | 1967/09/28 | 1967/09/23 | 1969/09/23 |
| Rousseau, Charles Odilon Roger | AEP | C | 1970/04/14 | 1970/01/14 | 1972/06/05 |
| Asselin, Pierre Léon Gérard | AEP | C | 1972/06/06 | 1972/08/24 | 1974/11/24 |
| Châtillon, Claude Charles-Edouard | AEP | C | 1975/10/21 | 1975/10/23 | 1978/06/12 |
| Duguay, Gilles Horace J. | AEP | C | 1978/07/13 | 1978/08/29 | 1980/09/03 |
| Denault, Jacques D.E. | AEP | C | 1980/07/10 | 1980/11/05 | 1982/07/31 |
| Saint-Pierre, Claude Jean | AEP | C | 1982/09/22 | 1982/10/12 | |
| Faguy, Marc | AEP | C | 1984/08/31 | 1984/11/19 | 1987/09/05 |
| Simard, André S. | AEP | C | 1987/09/10 | 1987/11/02 | 1989/07/16 |
| Leahy, Anne | AEP | C | 1989/10/12 | 1989/11/16 | 1992/03/10 |
| Després, Arsène A. | AEP | C | 1992/08/27 | 1993/01/05 | |
| Giguère, Pierre | AEP | C | 1995/07/04 | ||
| Baillargeon, Claude | AEP | C | 1998/07/15 | ||
| Perrault, Michel | H-C | C | 2000/07/27 | ||
| Savaria, Jules | H-C | C | 2003/09/15 | 2003/10/14 | |
| Lavoie, Jean-Pierre | H-C | C | 2006/09/20 | ||
| Pelletier, Jean-Carol | H-C | C | 2009/09/10 | ||
| Laramée, Benoît-Pierre | H-C | NC | 2011/08/16 |