| Chef de misssion | Titre | Carrière | Nomination | Présentation des lettres de créance | Fin de l'affectation |
| Kearney, John Doherty | EEMP | NC | 1945/12/05 | 1946/04/04 | 1946/00/00 |
| Laureys, Jean François Léon Henri | EEMP | NC | 1947/03/15 | 1947/07/12 | 1950/08/14 |
| Cornett, Donald Macalister | Chargé d'affaires a.i. | C | 1950/08/14 | 1952/04/07 | |
| McGreer, Edgar D'Arcy | EEMP | C | 1952/02/28 | 1952/04/07 | 1954/12/00 |
| Feaver, Herbert Frederick Brooks-Hill | EEMP | C | 1954/11/18 | 1954/12/11 | 1956/01/16 |
| Feaver, Herbert Frederick Brooks-Hill | AEP | C | 1956/01/11 | 1956/01/16 | 1958/07/17 |
| Watkins, John Benjamin Clark | AEP | C | 1958/08/30 | 1958/12/02 | 1960/00/00 |
| Allard, Hector | AEP | C | 1960/10/31 | 1961/01/12 | 1967/06/23 |
| Wershof, Max Hirsch | AEP | C | 1967/02/17 | 1967/07/17 | 1971/08/10 |
| Cornett, Donald Macalister | AEP | C | 1971/07/08 | 1971/09/16 | 1975/07/29 |
| Berlis, Norman Frederick Henderson | AEP | C | 1975/07/17 | 1975/10/07 | 1979/04/06 |
| Macpherson, Marion Adams | AEP | C | 1979/09/27 | 1979/12/20 | 1983/07/25 |
| Cullen, Thomas George | Chargé d'affaires a.i. | C | 1983/07/00 | 1984/01/00 | |
| Wang, Erik Benkestock | AEP | C | 1984/04/05 | 1984/01/05 | 1986/00/00 |
| Armstrong, Dorothy Jane | AEP | C | 1986/07/23 | 1986/11/06 | 1991/08/19 |
| MacLean, Ronald Stuart | AEP | C | 1991/00/00 | 1991/08/29 | 1992/10/29 |
| Hébert, Ernest | AEP | C | 1993/06/23 | 1993/03/02 | 1995/00/00 |
| Baker, Brian | AEP | C | 1995/05/03 | 1999/00/00 | |
| Simon, Mary May | AEP | NC | 1999/08/11 | 2001/00/00 | |
| Gagliano, Hon. Alfonso | AEP | NC | 2002/01/15 | 2004/02/10 | |
| Gregory, Fredericka | AEP | C | 2004/05/19 | 2004/09/22 | |
| Lundy, Peter | AEP | C | 2008/07/04 | ||
| Giroux, André François | AEP | NC | 2012/08/20 |